Investigation of Mechanical, Corrosion and Microstructural Behaviour of Heat Treated Cr-Modified Al-Mg-Si Alloy

Olusegun Olufemi Ajide

Department of Mechanical Engineering, University of Ibadan, Ibadan, Oyo State, Nigeria.

Temilade Ruth Adelakun

Department of Mechanical Engineering, University of Ibadan, Ibadan, Oyo State, Nigeria.

Itopa Godwin Akande *

Department of Automotive Engineering, University of Ibadan, Ibadan, Oyo State, Nigeria.

Temilola Taiwo Olugasa

Department of Mechanical Engineering, University of Ibadan, Ibadan, Oyo State, Nigeria.

Nikhil Kumar

School of Materials Science and Technology, Indian Institute of Technology (BHU), Varanasi-221005, India.

*Author to whom correspondence should be addressed.


Abstract

Despite the choice of Al-Mg-Si alloy as a material for innumerable industrial and structural applications, challenges such as undesired scratch resistance, formability and mechanical properties deterioration in saline environment hinders the extent of its application for automotive and aerospace components. Nevertheless, with the growing interest in the application of Al-Mg-Si alloy in automotive and aerospace industries, there is need for cautious control of thermal treatments and inclusion of alloying elements with requisite potentials for enhancing the microstructure and mechanical properties of the alloy. Chromium is known to improve strength and corrosion resistance in several applications. Therefore, this study focuses on the investigation of the effect of Cr particles inclusion in Al-Mg-Si alloy.  The effect of ageing heat treatment on selected properties of Al-Mg-Si-Cr alloy was also studied in this work. The Al-Mg-Si and Al-Mg-Si-Cr alloys were developed using a two-step stir casting technique. Chromium was added to Al-Mg-Si alloy at varying percentages of 0, 0.5, 1.0, 1.5, 2.0 and 2.5. All the samples were solution treated in an electric furnace at 500 oC for 30 minutes and water quenched. Then the samples were artificially aged at 210 oC for 3 hours and quenched in natural air. The hardness test revealed that the inclusion of Cr particles in Al-Mg-Si alloy samples increased hardness from 35.03 Kgf/mm2 (hardness of Al-Mg-Si-0%Cr alloy sample) to a maximum value of 126.54 Kgf/mm2 (hardness of Al-Mg-Si-1.5%Cr alloy sample). After heat treatment, the hardness of Al-Mg-Si-0%Cr alloy sample increased to 80.84 Kgf/mm2, while that of Al-Mg-Si-1.5%Cr alloy sample decreased slightly to 120.88 Kgf/mm2. The impact strength test also showed that the inclusion of Cr in Al-Mg-Si alloy increased impact strength from 9.52 J/mm2 (impact strength of Al-Mg-Si-0%Cr alloy sample) to a maximum value of 19.04 J/mm2 (impact strength of Al-Mg-Si-2.0%Cr alloy sample). After heat treatment, the impact strength of Al-Mg-Si-0%Cr alloy sample increased marginally to 10.09 J/mm2, while that of Al-Mg-Si-2.0%Cr alloy sample decreased slightly to 17.57 J/mm2. The tensile and electrochemical tests revealed that the heat-treated Al-Mg-Si-1.0%Cr alloy sample exhibited the highest tensile strength and lowest corrosion rate of 152 MPa and 0.0014 mm/year, respectively. The microstructural examination further revealed that the inclusion of Cr particles in Al-Mg-Si alloy improved its surface morphology. Al-Mg-Si-1.0%Cr alloy sample was adjudged to possess the best microstructural properties. Therefore, this sample is recommended as a potential material for machine tools and other structural or advanced manufacturing applications.

Keywords: Al-Mg-Si, Al-Mg-Si-Cr, chromium, mechanical properties, microstructure and corrosion rate


How to Cite

Ajide , O. O., Adelakun , T. R., Akande , I. G., Olugasa , T. T., & Kumar, N. (2023). Investigation of Mechanical, Corrosion and Microstructural Behaviour of Heat Treated Cr-Modified Al-Mg-Si Alloy. Journal of Engineering Research and Reports, 25(5), 55–70. https://doi.org/10.9734/jerr/2023/v25i5911

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References

Zhang X, Chen Y, Hu J. Recent advances in the development of aerospace materials. Progress in Aerospace Sciences. 2018;97:22-34.

Hung FS. Design of lightweight aluminum alloy building materials for corrosion and wear resistance. Emerging Materials Research. 2020;9(3):750-757.

Musfirah AH, Jaharah AG. Magnesium and aluminum alloys in automotive industry. Journal of Applied Sciences Research. 2012;8(9):4865-4875.

Jeong C, Leem J, Sheppard K, Choi CH. Air-impregnated nanoporous anodic aluminum oxide layers for enhancing the corrosion resistance of aluminum. Langmuir. 2015;31(40):11040-11050.

Barthwal S, Lim SH. Robust and chemically stable superhydrophobic aluminum-alloy surface with enhanced corrosion resistan-ceproperties. International Journal of Precision Engineering and Manufacturing-Green Technology. 2020;7(2):481-492.

Vengatesh P, Kulandainathan MA. Hierarchically ordered self-lubricating superhydrophobic anodized aluminum surfaces with enhanced corrosion resistance. ACS Applied Materials and Interfaces. 2015;7(3):1516-1526.

Tecchio P, McAlister C, Mathieux F, Ardente F. In search of standards to support circularity in product policies: A systematic approach. Journal of Cleaner Production. 2017;168:1533-1546.

Ghosh P, Yusop MZ, Satoh S, Subramanian M, Hayashi A, Hayashi Y, Tanemura M. Transparent and flexible field electron emitters based on the conical nanocarbon structures. Journal of the American Chemical Society. 2010;132(12):4034-4035.

Bhowmik A, Mishra D. A comprehensive study of an aluminum alloy AL-5052. Advance Physics Letter. 2016; 3(1):20-22.

Huang K, Marthinsen K, Zhao Q, Loge RE. The double-edge effect of second-phase particles on the recrystallization behaviour and associated mechanical properties of metallic materials. Progress in Materials Science. 2018;92:284-359.

Li XP, Wang XJ, Saunders M, Suvorova A, Zhang LC, Liu YJ, Sercombe TB. A selective laser melting and solution heat treatment refined Al–12Si alloy with a controllable ultrafine eutectic microstructure and 25% tensile ductility. Acta Materialia. 2015;95:74-82.

Zhang XY, Fang G, Leeflang S, Böttger AJ, Zadpoor AA, Zhou J. Effect of subtransus heat treatment on the microstructure and mechanical properties of additively manufactured Ti-6Al-4V alloy. Journal of Alloys and Compounds. 2018;735:1562-1575.

Santhosh R, Geetha M, Rao MN. Recent developments in heat treatment of beta titanium alloys for aerospace applications. Transactions of the Indian Institute of Metals. 2017;70(7):1681-1688.

Safarbali B, Shamanian M, Eslami A. Effect of post-weld heat treatment on joint properties of dissimilar friction stir welded 2024-T4 and 7075-T6 aluminum alloys. Transactions of Nonferrous Metals Society of China. 2018;28(7):1287-1297.

Mohamed AMA, Samuel FH. A review on the heat treatment of Al-Si-Cu/Mg casting alloys. Heat Treatment-Conventional and Novel Applications. 2012;55-72.

Liu P, Hu JY, Li HX, Sun SY, Zhang YB. Effect of heat treatment on microstructure, hardness and corrosion resistance of 7075 Al alloys fabricated by SLM. Journal of Manufacturing Processes. 2020;60: 578-585.

Jin S, Ngai T, Zhang G, Zhai T, Jia S, Li L. Precipitation strengthening mechanisms during natural ageing and subsequent artificial aging in an Al-Mg-Si-Cu alloy. Materials Science and Engineering: A. 2018;724:53-59.

Ma P, Zhan L, Liu C, Wang Q, Li H, Liu D, Hu Z. Pre-strain-dependent natural ageing and its effect on subsequent artificial ageing of an Al-Cu-Li alloy. Journal of Alloys and Compounds. 2019;790:8-19.

Engler O, Marioara CD, Aruga Y, Kozuka M, Myhr OR. Effect of natural ageing or pre-ageing on the evolution of precipitate structure and strength during age hardening of Al–Mg–Si alloy AA 6016. Materials Science and Engineering: A. 2019;759:520-529.

Prach O, Trudonoshyn O, Randelzhofer P, Körner С, Durst K. Effect of Zr, Cr and Sc on the Al–Mg–Si–Mn high-pressure die casting alloys. Materials Science and Engineering: A. 2019;759:603-612.

Li GJ, Guo MX, Wang Y, Zheng CH, Zhang JS, Zhuang LZ. Effect of Ni addition on microstructure and mechanical properties of Al–Mg–Si–Cu–Zn alloys with a high Mg/Si ratio. International Journal of Minerals, Metallurgy, and Materials. 2019;26(6):740-751.

Lv Z, Fu H, Xing J, Ma S, Hu Y. Microstructure and crystallography of borides and mechanical properties of Fe–B–C–Cr–Al alloys. Journal of Alloys and Compounds. 2016;662:54-62.

Ding L, Jia Z, Liu Y, Weng Y, Liu Q. The influence of Cu addition and pre-straining on the natural aging and bake hardening response of Al-Mg-Si alloys. Journal of Alloys and Compounds. 2016;688: 362-367.

Weng Y, Jia Z, Ding L, Muraishi S, Liu Q. Clustering behavior during natural aging and artificial aging in Al-Mg-Si alloys with different Ag and Cu addition. Materials Science and Engineering:A. 2018;732: 273-283.

Li C, Liu K, Chen XG. Improvement of elevated-temperature strength and recrystallization resistance via Mn-containing dispersoid strengthening in Al-Mg-Si 6082 alloys. Journal of Materials Science and Technology. 2020;39: 135-143.

Lu G, Nie S, Wang J, Zhang Y, Wu T, Liu Y, Liu C. Enhancing the bake-hardening responses of a pre-aged Al-Mg-Si alloy by trace Sn additions. Journal of Materials Science and Technology. 2020;40:107-112.

Odoh D, Mahmoodkhani Y, Wells M. Effect of alloy composition on hot deformation behavior of some Al-Mg-Si alloys. Vacuum. 2018;149:248-255.

Vilamosa V, Clausen AH, Borvik T, Skjervold SR, Hopperstad OS. Behaviour of Al-Mg-Si alloys at a wide range of temperatures and strain rates. International Journal of Impact Engineering. 2015;86:223-239.

Mikhailovskaya AV, Golovin IS, Zaitseva AA, Portnoi VK, Drottboom P, Cifre J. Effect of Mn and Cr additions on kinetics of recrystallization and parameters of grain-boundary relaxation of Al-4.9 Mg alloy. The Physics of Metals and Metallography. 2013;114(3):246-255.

Assaad A. Quench sensitivity of 6xxx aluminum alloys (Master's thesis, University of Waterloo);2016.

Zuo J, Hou L, Shi J, Cui H, Zhuang L, Zhang J. The mechanism of grain refinement and plasticity enhancement by an improved thermomechanical treatment of 7055 Al alloy. Materials Science and Engineering: A. 2017;702:42-52.

Kim B, Park CH, Kim HS, You BS, Park SS. Grain refinement and improved tensile properties of Mg–3Al–1Zn alloy processed by low-temperature indirect extrusion. Scripta Materialia. 2014;76: 21-24.

Ertug B, Kumruoglu LC. 5083 type Al-Mg and 6082 type Al-Mg-Si alloys for ship building. American Journal of Engineering Research. 2015;146-150.

Ji S, Watson D, Fan Z, White M. Development of a super ductile diecast Al–Mg–Si alloy. Materials Science and Engineering: A. 2012;556:824-833.

Fan XB, He ZB, Zhou WX, Yuan SJ. Formability and strengthening mechanism of solution treated Al–Mg–Si alloy sheet under hot stamping conditions. Journal of Materials Processing Technology. 2016; 228:179-185.

Man J, Jing L, Jie SG. The effects of Cu addition on the microstructure and thermal stability of an Al–Mg–Si alloy. Journal of Alloys and Compounds. 2007;437(1-2):146-150.

Sarraf M, Nasiri-Tabrizi B, Dabbagh A, Basirun WJ, Sukiman NL. Optimized nanoporous alumina coating on AA3003-H14 aluminum alloy with enhanced tribo-corrosion performance in palm oil. Ceramics International. 2020;46(6):7306-7323.

McCafferty E. Validation of corrosion rates measured by the Tafel extrapolation method. Corrosion Science. 2005;47(12):3202-3215.

Awe AA, Adedayo SM, Olabamiji TS. Design, development and performance evaluation of A 5-Ton capacity brinell hardness testing machine. Journal of Physics: Conference Series. 2019;1378(3):1-12.

Dutta A, Saha SK, Adhikari U, Banerjee P, Sukul D. Effect of substitution on corrosion inhibition properties of 2-(substituted phenyl) benzimidazole derivatives on mild steel in 1 M HCl solution: A combined experimental and theoretical approach. Corrosion Science. 2017;123: 256-266.

Fayomi OSI, Akande IG, Oluwole OO, Daramola D. Effect of water-soluble chitosan on the electrochemical corrosion behaviour of mild steel. Chemical Data Collections. 2018;17:321-326.

Lgaz H, Bhat KS, Salghi R, Jodeh S, Algarra M, Hammouti B, Essamri A. Insights into corrosion inhibition behavior of three chalcone derivatives for mild steel in hydrochloric acid solution. Journal of Molecular Liquids. 2017;238:71-83.

Abd-El-Nabey B.A, Goher YM, Fetouh HA, Karam MS. Anticorrosive properties of chitosan for the acid corrosion of aluminium. Portugaliae Electrochimica Acta. 2015;33(4):231-239.

Akande IG, Oluwole OO, Fayomi OSI. Optimizing the defensive characteristics of mild steel via the electrodeposition of ZnSi3-N4 reinforcing particles. Defence Technology. 2019;15(4):526-532.

Gupta RK, Malviya M, Verma C, Quraishi MA. Aminoazobenzene and diaminoazobenzene functionalized graphene oxides as novel class of corrosion inhibitors for mild steel: experimental and DFT studies. Materials Chemistry and Physics. 2017;198:360-373.

Akande IG, Fayomi OSI, Oluwole OO. Anticorrosion potential of inhibitive suphtrim drug on aluminium alloys in 0.5 M H2SO4. Journal of Bio-and Tribo-Corrosion. 2020;6(4):1-8.

Mirzakhani B, Payandeh Y. Combination of sever plastic deformation and precipitation hardening processes affecting the mechanical properties in Al–Mg–Si alloy. Materials and Design. 2015;68: 127-133.

Ashjari M, Feizi AJ. 7xxx aluminum alloys; strengthening mechanisms and heat treatment: a review. Material Sci and Eng Int J. 2018;2(2):49-53.

Pedrazzini S, Galano M, Audebert F, Collins DM, Hofmann F, Abbey B, Smith GDW. Strengthening mechanisms in an Al-Fe-Cr-Ti nano-quasicrystalline alloy and composites. Materials Science and Engineering: A. 2016;672:175-183.

Lodgaard L, Ryum N. Precipitation of dispersoids containing Mn and/or Cr in Al–Mg–Si alloys. Materials Science and Engineering: A. 2000;283(1-2):144-152.

Gül C, Çömez N, Çivi C, Durmuş H. Reliability analysis of brinell hardness results for aged alumix321/SiC composites. Transactions of the Indian Institute of Metals. 2019; 72(9): 2311-2318.

Wang AQ, Guo HD, Han, HH, Xie JP. Effect of solid solution and ageing treatments on the microstructure and mechanical properties of the SiCp/Al-Si-Cu-Mg Composite. Kemija u Industriji. 2017;66(7-8):345−351.

Aboulkhair NT, Maskery I, Tuck C, Ashcroft I, Everitt NM. The microstructure and mechanical properties of selectively laser melted AlSi10Mg: The effect of a conventional T6-like heat treatment. Materials Science and Engineering: A. 2016;667: 139-146.

Read N, Wang W, Essa K, Attallah MM. Selective laser melting of AlSi10Mg alloy: Process optimisation and mechanical properties development. Materials and Design (1980-2015). 2015;65:417-424.

Mozammil S, Karloopia J, Verma R, Jha PK. Effect of varying TiB2 reinforcement and its ageing behaviour on tensile and hardness properties of in-situ Al-4.5% Cu-xTiB2 composite. Journal of Alloys and Compounds. 2019;793:454-466.

Herrera‐Ramírez LC, Castell P, Castillo‐Rodríguez M, Fernández Á, Guzman de Villoria R. The effect of a semi‐industrial masterbatch process on the carbon nanotube agglomerates and its influence in the properties of thermoplastic carbon nanotube composites. Journal of Polymer Science Part B: Polymer Physics. 2017;55(2):189-197.

Wang PH, Sarkar S, Gulgunje P, Verghese N, Kumar S. Fracture mechanism of high impact strength polypropylene containing carbon nanotubes. Polymer. 2018;151:287-298.

Zhang H, Zhang Z. Impact behaviour of polypropylene filled with multi-walled carbon nanotubes. European Polymer Journal. 2007;43(8):3197-3207.

Rashed HM. Control of distortion in aluminium heat treatment. Fundamentals of Aluminium Metallurgy. Woodhead Publishing. 2018;495-524.

Ajide OO, Ogochukwu CD, Akande IG, Petinrin MO, Ismail OS, Oluwole OO, Oyewola OM. Production and characterisation of Al-Mg-Cr alloy for machine tool applications, Test Engineering and management. 2020;83:1-9.

Reddy AC, Zitoun E. Tensile properties and fracture behavior of 6061/Al2O3 metal matrix composites fabricated by low pressure die casting process. International Journal of Materials Sciences. 2011; 6(2):147-157.

Prabu SB, Karunamoorthy L, Kathiresan S, Mohan B. Influence of stirring speed and stirring time on distribution of particles in cast metal matrix composite. Journal of Materials Processing Technology. 2006; 171(2):268-273.

Balasubramanian I, Maheswaran R. Effect of inclusion of SiC particulates on the mechanical resistance behaviour of stir-cast AA6063/SiC composites. Materials and Design (1980-2015). 2015;65: 511-520.

Li W, Li S, Liu J, Zhang A, Zhou Y, Wei Q, Shi Y. Effect of heat treatment on AlSi10Mg alloy fabricated by selective laser melting: Microstructure evolution, mechanical properties and fracture mechanism. Materials Science and Engineering: A. 2016;663: 116-125.

Tian W, Li, Wang B, Liu J, Yu M. Pitting corrosion of naturally aged AA 7075 aluminum alloys with bimodal grain size. Corrosion Science. 2016;113:1-16.

Luo C, Albu SP, Zhou X, Sun Z, Zhang X, Tang Z, Thompson GE. Continuous and discontinuous localized corrosion of a 2xxx aluminium–copper–lithium alloy in sodium chloride solution. Journal of Alloys and Compounds. 2016;658:61-70.

Hafenstein S, Werner E. Pressure dependence of age-hardenability of aluminum cast alloys and coarsening of precipitates during hot isostatic pressing. Materials Science and Engineering: A. 2019;757:62-69.

Ajide OO, Otesile AO, Salau TAO, Ismail OS, Oyewola OM. Investigating effect of zinc content on the mechanical and corrosion responses of Al6063-SiC composite. Current Journal of Applied Science and Technology. 2017;22(3):1-10.

Ezatpour HR, Sajjadi SA, Sabzevar MH, Huang Y. Investigation of microstructure and mechanical properties of Al6061-nanocomposite fabricated by stir casting. Materials and Design. 2014;55:921-928.

Bermingham MJ, StJohn DH, Krynen J, Tedman-Jones S, Dargusch MS. Promoting the columnar to equiaxed transition and grain refinement of titanium alloys during additive manufacturing. Acta Materialia. 2019;168:261-274.

Lv J, Guo W, Liang T, Yang M. The effects of ball milling time and surface enriched chromium on microstructures and corrosion resistance of AISI 304 stainless steel. Materials Chemistry and Physics. 2017;197:79-86.

Fattah-Alhosseini A, Vafaeian S. Influence of grain refinement on the electrochemical behavior of AISI 430 ferritic stainless steel in an alkaline solution. Applied Surface Science. 2016;360:921-928.

Alizadeh A, Taheri-Nassaj E, Hajizamani M. Hot extrusion process effect on mechanical behavior of stir cast Al based composites reinforced with mechanically milled B4C nanoparticles. Journal of Materials Science and Technology. 2011;27(12):1113-1119.

Fayomi OSI, Joseph OO, Akande IG, Ohiri CK, Enechi KO, Udoye NE. Effect of CCBP doping on the multifunctional Al-0.5 Mg-15CCBP superalloy using liquid metallurgy

process for advanced application. Journal of Alloys and Compounds. 2019;783:246-255.

Akbari MK, Mirzaee O, Baharvandi HR. Fabrication and study on mechanical properties and fracture behavior of nanometric Al2O3 particle-reinforced A356 composites focusing on the parameters of vortex method. Materials & Design. 2013; 46:199-205.

Zhou X, Fu R, Fu D, Wang Y. Ultrasound frequency-dependent microstructures of electrodeposited Ni nanocrystals for modifying mechanical properties. Journal of Materials Science. 2020;55(30): 14980-15004.